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allied

academies

May 13-14, 2019 | Prague, Czech Republic

Chemistry and Medicinal Chemistry

9

th

World Congress on

Page 19

Asian Journal of Biomedical and Pharmaceutical Sciences | Volume 9

ISSN: 2249-622X

L

arge electrocaloric (EC) effect with a broad operational

temperature range is required and attractive in solid-state

cooling devices. In this work, a giant

EC

effect (ΔT ~ 20.7K) in

a broad temperature range ( ~ 110 K) was demonstrated in

relaxor antiferroelectric (AFE) Pb

0.97

La

0.02

(Zr

0.65

Sn

0.3

Ti

0.05

) O

3

(PLZST) sol-gel thin film. The use of the LaNiO

3

/Pt composite

bottom electrode may cause the in-plane residual thermal

tensile stress during the layer-by-layer annealing process,

which may be responsible for the large positive EC effect.

The coexistence of nanoscale multiple FE and AFE phases

leads to the great dielectric relaxor dispersion around the

dielectric peak, which may be ascribed to the broad EC

operational temperature range. These newly-discovered

properties in the PLZST thin films suggest thismultifunctional

material having a great potential for applications in modern

solid-state cooling.

Speaker Biography

Qi Zhang is a senior lecturer in Cranfield University, UK and a professor

in Wuhan University of Technology, Wuhan, China. He has his expertise

in functional materials. He was one of the initiators of the thin film

electrocaloric effect, which could develop. He has authored or co-

authored over 200 papers, edited one book and 10 book chapters.

He has an h factor of 30. He is a fellow and charted scientist in IOM3.

His main areas of research are within synthesis of nanomaterials for

electrochemical energy storage, fabrication of transparent conducting

thin films and sol-gel synthesis and structural characterization of

ferroelectric thin films for electrocaloric cooling. He was the recipient

of the Royal Society Brian Mercer Feasibility Award.

e:

q.zhang@cranfield.ac.uk

Qi Zhang

Biaolin Peng

Cranfield University, UK

Giant electrocaloric effect found in the relaxor PLZST thin films with

the coexistence of antiferroelectric and ferroelectric phases in a

broad temperature range

Qi Zhang et al., Asian J Biomed Pharmaceut Sci, Volume:9

DOI: 10.4066/2249-622X-C2-019

Notes: