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Journal of Biotechnology and Phytochemistry
Volume 1 Issue 3
Chemistry World 2017
Notes:
Page 51
November 13-15, 2017 Athens, Greece
7
th
World Congress on
Chemistry
Relativistic origin of classical thermodynamics as an
alternative to the concept of probability
A Yu Zakharov
Yaroslav-the-Wise Novgorod State University, Russia
T
he problem of the non-contradictory microscopic
foundation of both thermodynamics and kinetics remains
unsolved. Thus, statistical mechanics is an ill-posed theory. In
addition to internal contradictions, there are several difficult
fundamental problems in this theory suchas (i) the equivalence
criteria for the statistical ensembles are not known, (ii)
there are no exact methods or a priori accuracy estimates of
approximate methods for calculating partition functions, (iii)
the problem of closure of equations for partial distribution
functions leads to use uncontrolled additional probabilistic
hypotheses such as weakening correlations principle. The
purpose of this study is to develop a method for probability-
free describing the evolution of many-particle systems with
account relativistic effects. In our papers, a new description of
the evolution of a systemof particles with retarded interactions
is proposed. The qualitative properties of the solutions of this
relativistic equation with respect to the microscopic density
are investigated. It is proved that the solutions possess the
property of irreversibility in time. Therefore, there is no need
to use any kind of probabilistic concepts in the microscopic
foundation of classical thermodynamics. The further
purpose of our research is to construct a microscopic kinetic
theory of many-particle systems, including the processes
of thermodynamic equilibration at different scales, the
calculation of thermodynamic and kinetic properties.
Biography
A Yu Zakharov has completed his PhD from Donetsk Physico-Technical
Institute, Academy of Sciences of Ukrainian SSR and Postdoctoral studies from
Donetsk Polytechnical Institute, USSR. He is Professor in Yaroslav-the-Wise
Novgorod State University. He has published more than 70 papers in reputed
journals and six monographs.
anatoly.zakharov@novsu.ruA Yu Zakharov, J Biotech and Phyto 2017