chemistry-world-2017-scientifictracks-abstracts

22 / 30

alliedacademies
Journal of Biotechnology and Phytochemistry
Volume 1 Issue 3 Chemistry World 2017
Notes:
Page 42
November 13-15, 2017 Athens, Greece
7th World Congress on
Chemistry
Visible light–mediated synthesis of organophosphorus
compounds: synthetic and mechanistic investigations
Sami Lakhdar
University of Caen Basse-Normandie, France
Reactions involving phosphorus centered radicals play
a pivotal role in the construction of organophosphorus
ligands, biologically active molecules and p- conjugated
molecules. Common synthetic approaches for the generation
of such radicals imply the use of harsh reaction conditions.
In this communication, we show that access to a large variety
of organophosphorus compounds can be achieved under
mild reaction conditions through: i) visible light photoredox
catalysis or ii) visible light irradiation of Electron–Donor-
Acceptor complexes (EDA). The scope and limitations of
these methods will be discussed with a special focus on their
mechanistic aspects.
Recent Publications
1. D E C Corbridge (2013) Phosphorus: Chemistry,
Biochemistry and Technology, 6th ed, CRC Press:
Boca Raton, FL.
2. L D A Quin (2000) Guide to Organophosphorus
Chemistry; Wiley Interscience: New York.
3. V Quint, F Morlet-Savary, J F Lohier, J Lalevée,
A C Gaumont and S Lakhdar (2016) Metal-free,
visible light-photocatalyzed synthesis of benzo[b]
phosphole oxides: synthetic and mechanistic
investigations. Journal of American Chemical
Society 138(23):7436–7441.
4. L Noël-Duchesneau, E Lagadic, F Morlet-Savary,
J F Lohier, I Chataigner, M Breugst, J Lalevée, A C
Gaumont and S Lakhdar (2016) Metal-free synthesis
of 6-phosphorylated phenanthridines: synthetic and
mechanistic insights. Organic Letters 18(22):5900–
5903.
5. G Fausti, F Morlet-Savary, J Lalevée, A C Gaumont
and S Lakhdar (2017) Chemistry- A European
Journal 23:1–6.
Biography
Sami lakhdar is working as a professor at University of Caen Basse-Normandie,
France. He has his research experience in the field of organic and inorganic
chemistry
Sami Lakhdar, J Biotech and Phyto 2017