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Page 46

allied

academies

November 22-23, 2018 | Paris, France

Journal of Materials Science and Nanotechnology | Volume: 2

Materials Physics and Materials Science

International Conference on

High purity diamond single crystals and their possible applications in hi-tech areas

Vladimir Blank

Technological Institute for Superhard and Novel Carbon Materials, Russia

D

uring the past decade, the technologies of perfect diamond

single crystals, including semiconductor ones, have been

developing rapidly. However, despite the 50ct and above

success rate in the single crystal growthprocesses, theprospects

of diamond single crystals application in modern electronics

and other high-tech areas remain undiscovered. There are the

followingmainmethods for obtaining diamond crystals: growth

at high pressures and temperatures (HPHT) and gas-phase

synthesis (CVD). Both methods have a number of advantages

and disadvantages. In HPHT processes, it is possible to obtain

structurally perfect crystals, but the diamond size is limited by

the dimensions of the high-pressure cell. In the case of CVD,

the growth volume can be much larger, and it is easier to apply

doping in the synthesis of semiconductor crystals, but still, it is

not yet possible to produce dislocation-free diamonds.

Currently, there are several main hi-tech directions where we

can anticipate successful use of diamonds.This is primarily

passive electronics: diamond heat sinks. This is associated with

a sharp decrease in the cost of the diamond itself, an increase

in its size and in its thermal

conductivity.On

the other hand, we

can now establish some new directions that have emerged on

the basis of the successes in the perfect diamond single crystals

synthesis:

- X-ray optics, including the creation of X-ray lasers on free

electrons

- Extreme electronics, Schottky diodes and a β-decay diamond

battery; sensors of nuclear radiation, high-temperature sensors

- acoustoelectronics, including resonators with a frequency of

up to 40GHz

- quantum crystals, quantum computers, controlled formation

of NV and other centers in diamond

- single-crystal diamond tools, including those combined with

laser radiation, as well as for application inmicro- and nanoscale

The research carried out at FSBI TISNCM in these and other

fields showed high potential for the use of perfect diamonds.

Thus, in 2012 a free-electron X-ray laser using diamond optics

was launched in the US for the first time in the world; later

beam dividers, high-resolution spectrometers, focusing lenses

and other devices were created

thereupon.In

2017, a β-decay

diamond battery was tested, and an output power of 50μWt/

cm

3

was

obtained.In

2014, p-type diamond single crystals

were synthesized, and their crystallization and electronic

structures were studied showing that their physical properties

are due to the formation of B-C layers.These and a number

of other experimental results open up new horizons for using

high-purity diamond single crystals, including semiconductor

crystals, in the hi-tech industry comprising electronics, nuclear

and medical equipment.

e:

vblank@tisnum.ru