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Page 30
Journal of Biotechnology and Phytochemistry
Volume 1, Issue 2
Notes:
Plasma Chemistry 2017
November 13-14, 2017 Paris, France
5
th
International Conference on
PLASMA CHEMISTRY AND
PLASMA PROCESSING
María Dolores Calzada, J Biot Phyt 2017
High-quality graphene production from ethanol
decomposition using a microwave plasma
torch
G
raphene is a perfect two-dimensional material
with important electrical, mechanical and chemical
properties that make this material suitable for a
wide range of applications in different scientific and
technological fields. Thus, it has been successfully used
for manufacturing solar cells or as support for catalysts
in the electrodes of fuel cells. Conventional methods as
Chemical vapour deposition (CVD) and Liquid phase
exfoliation (LPE) have both been applied for graphene
production at industrial level. However, microwave
plasmas have been reported as efficient, clean, eco-
friendly and scalable technology for this purpose using
alcohols as precursors. Microwave plasma torches
have demonstrated the capability to dissociate the
molecules introduced into the discharge, giving place
to atoms and radicals. These species can recombine
at the plasma exit forming different products to those
used as precursors. In microwave plasma torches, the
reactions in which the plasma species are involved
depend on plasma parameters such as densities and
temperatures, whose values can be modified acting on
operational conditions used to create and maintain the
plasma, thus offering an important degree of control
over the final products. Besides, non-intrusive emission
spectroscopy techniques can be used to identify the
species and radicals formed into the plasma during
the precursor decomposition. This fact contributes to
understanding the key factors for graphene synthesis
using plasma technology. A microwave plasma torch,
so-called TIAGO (Torche à Injection Axiale sur Guide
d’Ondes), has been used to obtain high-quality graphene
2-7 layers utilizing Ar and ethanol as carrier gas and
carbon precursor, respectively. In this way, grapheme
powder is directly formed in a single step without
requiring any metal catalyst to induce the growing
process. In addition, the device and procedure can be
escalated at industrial level, adding a new technique for
graphene production to those already available.
Biography
María Dolores Calzada has completed her PhD degree in plasma physics from
the University of Seville in 1994. She carried out postdoctoral in Group of Plasma
Physics Department at University of Montreal, Canada. Since 1997, she joined the
department of physics at University of Córdoba, Spain and she is full professor from
2012. Currently, she is Head of the laboratory in innovation in plasmas (LIPs) with
research interests on the implementation of new spectroscopy methods for low-
temperature plasmas and the application of these ones into hydrogen production,
graphene synthesis, analytical chemistry, food conservation, and material
treatment.
md.calzada@uco.esMaría Dolores Calzada
University of Cordoba - Rabanales Campus, Spain