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Materials-Metals 2017

Page 57

November 16-17, 2017 Paris, France

13

th

Annual Conference on

Materials Science, Metal and Manufacturing

Journal of Materials Science and Nanotechnology

Volume 1 Issue 2

SiC nanowires/ribbons reinforced high-

temperature ceramic coatings

Yanhui Chu

South China University of Technology, China

C

arbon/carbon (C/C) composites are prone to oxidize

and ablate at elevated temperatures, which limits their

applications as high-temperature structural materials. The

ceramic coatings are considered to be the effective methods to

solve this problem. However, the intrinsic brittleness of these

coatings and the mismatch of the poor interfacial bonding

between these coatings and C/C substrate often give rise to

the cracking of the coatings, which results in the failure of the

coatings. To solve these problems, in our work, the ceramic

coatings reinforced by the well-dispersion SiC nanowires/

ribbons with different morphology and aspect ratios were

proposed and prepared by chemical vapor deposition, in-situ

synthesis and pack cementation. The as-prepared coatings

possessed the excellent oxidation protective ability, which

achieved the oxidation protective of silicon-based ceramic

coatings for C/C composites between 1500 °C and room

temperature. Our study not only revealed the traditional

toughening mechanisms of SiC nanowires/ribbons including

nanowire/ribbon pull-out, nanowires/ribbon bridging, crack

deflection and microcrack toughneing, but also revealed the

novel toughening mechanisms of SiC nanowires including

the plasticity deformation of the nanowires, the plasticity

fracture at the interface of the nanowire-matrix, and the

generated special mechanical interlocking. In addition, our

study also discovered that the interfacial bonding strength

of carbon and ceramic materials with other materials was

improved significantly by in-situ synthesizing SiC nanowires/

ribbons on their surface, and revealed the novel interface

anchoring mechanisms of SiC nanowires/ribbons involving

the interfacial bonding anchoring and the mechanical

interlocking anchoring.

chuyh@scut.edu.cn

Mater Sci Nanotechnol 2017, 1:2