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Page 21

S e p t e m b e r 2 4 - 2 6 , 2 0 1 8 | B u d a p e s t , H u n g a r y

OF EXCELLENCE

IN INTERNATIONAL

MEETINGS

alliedacademies.com

YEARS

Magnetic Materials 2018

Materials Science and Nanotechnology

|

Volume 2

MAGNETISM AND

MAGNETIC MATERIALS

2

nd

International Conference on

Chenglong Jia, Mater Sci Nanotechnol 2018, Volume 2

ROOM TEMPERATURE SINGLE PHASE

MULTIFERROIC AURIVILLIUS COMPOUND

Chenglong Jia

Lanzhou University, China

M

ultiferroics (MFs) have attracted great research interest due to

the coexistence of ferroelectric and magnetic ordering, as well as

magnetoelectric (ME) coupling. At present, there is a very limited number of

single-phase MFs known and these are still far from practical applications.

In single-phase MFs, the simultaneous presence of electric and magnetic

dipoles does not guarantee strong (ME) coupling, as the microscopic

mechanisms of ferroelectricity and magnetism are quite different and do

not intrinsically interact with each other. Here we show that in the Aurivillius

system Bi3.25La0.75Ti3-2xNbxFex/2Cox/2O12, the x=0.25 composition is

ferroelectrically and ferromagnetically active at room temperature. A single-

phase structure was supported by XRD, SEM/EDX and neutron diffraction

data. Clear ME couplings were observed in this single-phase material at

room temperature, where the magnetic iron and cobalt ions contribute to

ferroelectric polarization and magnetic moment simultaneously. The results

of structural, electrical and magnetic measurements are supported by first

principle calculations. This discovery of room temperature multiferroic

activity in this system will help to guide the design of room temperature

single-phase MFs with strong ME coupling for sensors and solid-state

memory applications.

Figure.1: Ferroelectric domain switching under magnetic field in BFCT25. (a)

topography and (d) vertical PFM phase at zero magnetic field; (b) topography

and (e) vertical PFM phase at +2000 Oe; (c) topography and (f) vertical PFM

phase at -2000 Oe via FMR.

Chenglong Jia is currently working as a Professor at

Lanzhou University, China. He was the distinguished

visiting fellow of the Royal Academy of Engineering,

UK (2015). He is the Deputy-Director of Key Laborato-

ry for Magnetism and Magnetic Materials of the Min-

istry of Education, Lanzhou University, China. He has

published more than 50 papers in reputed journals

and has been serving as an Editorial Board Member

of repute.

cljia@lzu.edu.cn

BIOGRAPHY

Recent Publications

1. Li Zheng et al., (2016). Room

temperature magnetoelectric coupling

in intrinsic multiferoic Aurivillius phase

textured ceramics. In Dalton Trans. 45:

14049.

2. Jia C L et al., (2014). Mechanism of

interfacial magnetoelectric coupling in

composite multiferroics. Phys. Rev. B

90: 054423.

3. Jia C L et al., (2007). Microscopic

theory of spin-polarization coupling in

multiferroic transition-metal oxides.

Phys. Rev. B 76: 144424.

4. Jia C L et al., (2006). Bond electronic

polarization induced by spin. Phys.

Rev. B 74: 224444.