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academies
November 22-23, 2018 | Paris, France
Journal of Materials Science and Nanotechnology | Volume: 2
Materials Physics and Materials Science
International Conference on
Obtaining of graphene/polymer composites by hydrosilylation reaction for SLA printer
Natia Jalagonia
Vekua Sukhumi Institute of Physics and Technology, Georgia
T
hree-dimensional (3D) printing is often considered
synonymous with additive manufacturing. Several types
of 3D printers are known where we usually used polymers
are. Stereolithography (SLA) employs a single beam laser to
polymerize or crosslink a photopolymer resin. By drawing on
the liquid photopolymer resin with a light beam, thin layers
of polymer are stacked layer by layer. Elastomer based on
polydimethysiloxanes (PDMS) are important class of materials,
because of properties such as chemical inertness, flexibility,
optical transparence, also they have a very low surface tension
(20.4mN/m) and glass transition temperatures (146K). it is
possible to print a support material that holds the PDMS
prepolymer in place until it can be cured by UV light using a
photoactivecross-linkingagent. It ispossibletograftphotoactive
group on PDMS backbone and obtain new UV curable polymer.
The aimof presentedwork is obtaining of photopolymers based
on PDMS. For purpose, we have conducted hydrosilylation
reaction of polymethylhydrosiloxane (PMHS) with allyl acrylate
and vinyltriethoxysilane in the presence Karstedt’s catalyst in
Toluene. Obtained polymer is liquid which are well soluble in
organic solvents with specific viscosity ηsp � 0.4. The end of
reactionwas testedby FTIR, where peak at 1260 cm
-1
disappears
which belongs to Si-H bonds. After this the polymer distilled in
vacuum, cross-linking agent was adding about 1% and curried
by UV during 1h.
Speaker Biography
Natia Jalagonia has completed her PhD at the age of 31 years from Tbilisi State
University, Georgia. She is the head of Chemical Technology Laboratory of Ilia Vekua
Sukhumi Institute. She has over 30 publications.
e:
n.jalagonia@sipt.org.ge